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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 1995, том 5, выпуск 6, страницы 237–238 (Mi mendc5119)

Эта публикация цитируется в 5 статьях

Polyhydrate 1,10-Diaza-18-crown-6·8.25H2O

K. A. Udachina, J. Lipkowskib

a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

Аннотация: The phase diagram of the system 1,10-diaza-18-crown-6–H2O has been studied; polyhydrate 1,10-diaza-18-crown-6-8.25H2O, which melts incongruently at 16.0 °C, has been found in this system. Each cavity of the three-dimensional framework made of water molecules accommodates four molecules of crown ether; the hydrate has the following crystallographic parameters: a = 18.848(2), c= 13.159(2) Å (T = −100°C), space group P42/n and Z = 8.

Язык публикации: английский

DOI: 10.1070/MC1995v005n06ABEH000545



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