Yu. A. Azev, I. P. Loginova, O. L. Guselnikova, S. V. Shorshnev, V. L. Rusinov, O. N. Chupakhin, “Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles”, Mendeleev Commun., 1994, том 4, выпуск 3,страницы 104

Эта публикация цитируется в 7 статьях

Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles

Yu. A. Azev^a, I. P. Loginova^b, O. L. Guselnikova^b, S. V. Shorshnev^a, V. L. Rusinov^c, O. N. Chupakhin^d

^a Ural Scientific Research Institute of Technology of Medical Preparations, Ekaterinburg, Russian Federation
^b Urals Polytechnical Institute, Ekaterinburg, Russian Federation
^c Department of Organic Chemistry, Urals State Technical University, Ekaterinburg, Russian Federation
^d I. Ya. Postovsky Institute of Organic Synthesis, Urals Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Аннотация: The reaction of 2,4-diazido-s-triazines 1 with an equimolar amount or a two-fold molar excess of ethyl cyanoacetate in the presence of triethylamine in DMF affords the corresponding mono- 2 or diamino derivatives of s-triazine 3; on heating 2,4-diazido-s-triazines 1a–d with a two-fold molar excess of acetoacetone or ethyl acetoacetate in the presence of triethylamine in ethanol the corresponding 1,2,3-triazolo-s-triazines 4a–f are formed.

Язык публикации: английский

DOI: 10.1070/MC1994v004n03ABEH000371