V. I. Minkin, M. S. Korobov, L. E. Nivorozhkin, O. E. Kompan, R. Ya. Olekhnovich, G. S. Borodkin, Yu. T. Struchkov, “Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a ZnII Centre”, Mendeleev Commun., 1993, том 3, выпуск 1,страницы 2

Эта публикация цитируется в 6 статьях

Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn^II Centre

V. I. Minkin^a, M. S. Korobov^a, L. E. Nivorozhkin^a, O. E. Kompan^a, R. Ya. Olekhnovich^a, G. S. Borodkin^a, Yu. T. Struchkov^b

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The associative inner-nucleophile assisted mechanism of inversion of tetrahedral configuration at the metal centre in bis-chelate Zn^II complexes based on alterdentate ligands, N-alkylimines of 2,5-diformylpyrrole, has been proved by dynamic ¹H, ¹³C, ¹⁵N NMR spectroscopic and X-ray crystallographic studies.

Язык публикации: английский

DOI: 10.1070/MC1993v003n01ABEH000192