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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 1993, том 3, выпуск 5, страницы 217–219 (Mi mendc5345)

Эта публикация цитируется в 1 статье

Stereoselective Synthesis of (1R,4R,6S)-6-(Dibromoaluminio)-7-(methoxymethyl)menth-2-ene and further Preparation of trans-7-(Methoxymethyl)menth-2-ene Hydroxy- and Oxo-derivatives

E. V. Gorobetsa, A. V. Kutchina, G. A. Tolstikovb

a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: (1R,4R,6R)- and (1R,4R,6S)-7-(Methoxymethyl)menth-2-en-6-ol 7 and 8, (1R,4R)-7-(methoxymethyl)menth-2-en-6-one 10, (1 R,4R)-7-(methoxymethyl)menth-2-ene 5 and their saturated analogues have been synthesized from (1 R,4R,6S)-6-(dibromoaluminio)-7-(methoxymethyl)menth-2-ene 3, prepared under hydroaiumination of the methyl ether of 2-{(1 R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl}ethanol with the LiAIH4·3AIBr3 system.

Язык публикации: английский

DOI: 10.1070/MC1993v003n05ABEH000302



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