A. M. Turuta, A. V. Kamernitskii, N. E. Voishvillo, N. V. Jlantiashvili, A. P. Krymov, N. V. Domrachev, “Use of 20,20-Dimethylacetal Protection in Microbial Hydroxylation and Dehydrogenation of Steroids”, Mendeleev Commun., 1991, том 1, выпуск 3,страницы 113

Эта публикация цитируется в 5 статьях

Use of 20,20-Dimethylacetal Protection in Microbial Hydroxylation and Dehydrogenation of Steroids

A. M. Turuta^a, A. V. Kamernitskii^a, N. E. Voishvillo^a, N. V. Jlantiashvili^a, A. P. Krymov^b, N. V. Domrachev^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b All-Russia Scientific Centre of Biologically Active Compounds, Moscow region, Russian Federation

Аннотация: The 20,20-dimethylacetal group proposed for protection of 20-oxo group in 21-hydroxylation of steroids by hypervalent iodine compounds has been successfully used to hamper side reactions in microbial 9α- and 11β-hydroxylation and 4-dehydrogenation of 21-hydroxy-16α,17α-epoxypregnanes by Rhodococcus sp., Curvularia Iunata and Corynebacterium mediolanum cultures.

Язык публикации: английский

DOI: 10.1070/MC1991v001n03ABEH000069