V. Ya. Lee, T. Meguro, O. A. Gapurenko, R. M. Minyaev, V. I. Minkin, H. Gornitzka, A. Sekiguchi, “Phosphatetrasilatricyclo[2.1.0.02,5]pentane”, Mendeleev Commun., 32:1 (2022), 33

Эта публикация цитируется в 2 статьях

Communications

Phosphatetrasilatricyclo[2.1.0.0^2,5]pentane

V. Ya. Lee^a, T. Meguro^a, O. A. Gapurenko^b, R. M. Minyaev^b, V. I. Minkin^b, H. Gornitzka^c, A. Sekiguchi^a

^a Department of Chemistry, University of Tsukuba, Tsukuba, Jupan
^b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^c Université de Toulouse, Toulouse, France

Аннотация: The phosphatetrasilatricyclo[2.1.0.0^2,5]pentane cage compound was synthesized by the reaction of the tetrasilacyclobutadiene dianion dipotassium salt precursor with PCl₃. The structure, bonding nature, and mechanism of formation of the title compound were studied both experimentally (NMR, X-ray) and computationally (DFT).

Ключевые слова: DFT calculations, housene, phosphorus, silicon, tricyclo[2.1.0.0²⁵]pentane, X-ray diffraction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.01.009

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