L. A. Bulygina, N. S. Khrushcheva, K. A. Lyssenko, A. S. Peregudov, “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction”, Mendeleev Commun., 2022, том 32, выпуск 3,страницы 331

Эта публикация цитируется в 5 статьях

Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

L. A. Bulygina^a, N. S. Khrushcheva^a, K. A. Lyssenko^bc, A. S. Peregudov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Аннотация: New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclopalladation with Li2PdCl or Na2PdCl4 and sodium acetate in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.

Ключевые слова: unsymmetrical pincer complexes, palladium complexes, ferrocene, bicyclic ligand precursor, Suzuki reaction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.05.012