D. A. Kulagina, A. S. Goryaev, I. N. Chernyshov, S. V. Sysolyatin, “Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane”, Mendeleev Commun., 32:3 (2022), 349

Communications

Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane

D. A. Kulagina, A. S. Goryaev, I. N. Chernyshov, S. V. Sysolyatin

Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation

Аннотация: Nitration of N-benzylated 2,4,6,8,10,12-hexaazaisowurtzitane derivatives occurs selectively at para-positions of the benzyl groups. The best reagent for this reaction is ammonium nitrate in sulfuric acid.

Ключевые слова: hexaazaisowurtzitanes, cage compounds, nitration, nitrating mixtures, benzyl groups, selective reaction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.05.019

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