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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2024, том 34, выпуск 1, страницы 137–139 (Mi mendc67)

Communications

Features of ignition of mixtures of hydrogen with hydrocarbons (C2, C3 and C5) over rhodium and palladium at pressures of 1–2 atm

N. M. Rubtsova, V. I. Chernysha, G. I. Tsvetkova, K. Ya. Troshinb, I. O. Shamshinb

a A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation


Аннотация: It was found that the reactivity of a hydrocarbon during oxidation catalyzed by a noble metal begins to play a significant role with an increase in the number of carbon atoms in its molecule. Thus, the process of hydrocarbon mass transfer to (or on) the catalyst surface determines the oxidation rate.

Ключевые слова: catalytic, ignition, delay, limit, rhodium, palladium, hydrogen, hydrocarbon.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.01.042



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