E. A. Merkulova, A. V. Kolobov, K. A. Lyssenko, V. G. Nenajdenko, “Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone”, Mendeleev Commun., 2022, том 32, выпуск 3,страницы 384

Эта публикация цитируется в 5 статьях

Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone

E. A. Merkulova^a, A. V. Kolobov^a, K. A. Lyssenko^b, V. G. Nenajdenko^b

^a Yaroslavl State Technical University, Yaroslavl, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Аннотация: The reaction distyryl thioketone with donor alkenes (norbornene and styrene) gives adducts of the hetero-Diels–Alder reaction. In the case of maleic acid derivatives, a tandem reaction occurs which leads to polycyclic derivatives of 3,4-dihydro-2H-thiopyran. The stereochemical features of the ongoing transformations were examined.

Ключевые слова: 3,4-dihydro-2H-thiopyrans, hetero-Diels–Alder reaction, dienes, dienophiles, diene-transmissive reactions, Lawesson’s reagent, thioketones, enethiones.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.05.031