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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2022, том 32, выпуск 5, страницы 693–696 (Mi mendc771)

Communications

Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane – air mixtures

N. M. Rubtsova, G. I. Tsvetkova, V. I. Chernysha, K. Ya. Troshinb

a A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation


Аннотация: Using the combustion of n-pentane – air mixtures as an example, it was shown that thermoacoustic regimes of ignition disappear in the presence of a platinum surface, which generates catalytic centers propagating into the volume. Thus, the platinum catalyst eliminates a certain stage of kinetic mechanism, and the negative temperature coefficient phenomenon vanishes. In the presence of a palladium catalytic surface that does not generate catalytic centers propagating into the volume, the phenomenon of a negative temperature coefficient occurs.

Ключевые слова: ignition, premixed, n-pentane–air, thermoacoustic, platinum, palladium, negative temperature coefficient.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.09.043



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