F. T. Sadykova, T. P. Zosim, I. R. Ramazanov, U. M. Dzhemilev, “Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines”, Mendeleev Commun., 2021, том 31, выпуск 1,страницы 46

Эта публикация цитируется в 1 статье

Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines

F. T. Sadykova, T. P. Zosim, I. R. Ramazanov, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Аннотация: The reaction of N,N-diisopropyl-N-propargylamines with Et3Al/MXn system (MXn = CuCl, CuBr, ZnCl2, ZnI2, CdI2, TiCl4, ZrCl4, VCl5, TaCl5) in CH2Cl2 proceeds as an intramolecular red-ox hydride transfer affording N-dealkylated N-isopropyl-N-allylamines, allenes being formed as side products. The highest chemoselectivities and yields (71–89%) were attained by the application of new ZnI2/(MeAlO)n system.

Ключевые слова: allylic amines, hydride transfer, propargylic amines, methylalumoxane, zinc iodide, N-dealkylation.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.01.013