S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko, “Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction”, Mendeleev Commun., 2021, том 31, выпуск 4,страницы 548

Эта публикация цитируется в 3 статьях

Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction

S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: An efficient and practical method for a scalable synthesis of 3-arylbutadiene sulfones deals with the ligand-free Heck–Matsuda reaction of sulfolene with aryldiazonium tetrafluoroborates followed by triethylamine-promoted double bond shift.

Ключевые слова: arylation, cross-coupling, Pd-catalysis, butadiene, sulfolene, aryldiazonium salts.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.07.037