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ЖУРНАЛЫ // Наносистемы: физика, химия, математика // Архив

Наносистемы: физика, химия, математика, 2020, том 11, выпуск 4, страницы 462–467 (Mi nano546)

CHEMISTRY AND MATERIAL SCIENCE

Solubility phase equilibrium in ternary system fullerenol C$_{60}$(OH)$_{24}$ and praseodymium salt: PrCl$_3$-C$_{60}$(OH)$_{24}$-H$_2$O at 25$^\circ$ C

G. A. Glushneva, Ayat Kanbara, V. A. Keskinova, N. A. Charykovba, K. N. Semenovacd, Z. K. Shaimardanove, B. K. Shaimardanovae, N. A. Kulenovae, D. G. Letenkof

a St. Petersburg State Technological Institute (Technical University), Moskovsky prospect, 26, St. Petersburg, 190013, Russia
b St. Petersburg Electrotechnical University “LETI”, ul. Professora Popova 5, 197376 St. Petersburg, Russia
c Pavlov First St. Petersburg StateMedical University L’va Tolstogo str. 6–8 St. Petersburg, 197022, Russia
d St. Petersburg State University, 7/9 Universitetskaya emb., St. Petersburg, 199034, Russia
e D. Serikbayev East Kazakhstan state technical university, A. K. Protozanov Street, 69, Ust-Kamenogorsk, 070004, The Republic of Kazakhstan
f St. Petersburg State University of Architecture and Civil Engineering (SPSUACE), 2nd Krasnoarmeiskaya St. 4, 190005 St. Petersburg, Russia

Аннотация: Solubility diagram was investigated by the method of saturation in ampules at 25 $\pm$ 0:02$^{\circ}$C for 4 hours. The solubility diagram of the PrCl$_{3}$-C$_{60}$(OH)$_{24}$-H$_{2}$O ternary system at 25$^{\circ}$C occurs as simple eutonics, consisting of two branches, corresponding to the crystallization of crystalhydrates: PrCl$_{3}$ $\cdot$ 7H$_{2}$O and C$_{60}$(OH)$_{24}$ $\cdot$ 18H$_{2}$O. The diagram contains one non-variant point each - eutonics, which corresponds to saturation with pair of crystal-hydrates simultaneously. The diagram also contains very short branch of PrCl$_{3}$ $\cdot$ 7H$_{2}$O crystallization, and long branch of C$_{60}$(OH)$_{24}$ $\cdot$ 18H$_{2}$O, where the effect of fullerenol salt-out is distinctly observed.

Ключевые слова: fullerene C60, arginine, octo-adduct, lutetium chloride, solubility diagram, ternary system, simple eutonic.

Поступила в редакцию: 06.04.2020
Исправленный вариант: 29.05.2020

Язык публикации: английский



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