Аннотация:
A new line list transition for the water molecule is presented. The line lists is created on the basis of VoTe calculations using cutoff values of 25000 cm$^{-1}$ in transition wav number and $J_{\operatorname{max}}$ = 50. Calculations use the high accuracy, empirical potential energy surface (PES) of Bubukina et al. LTP2011 and the CVR water dipole moment surface (DMS) of Lodi et al. (2011). Vibration – rotation energy levels up to $J$ = 50 are computed using DVR3D; a novel method of labeling is used which allows more thorough labelling of the energy levels with approximate vibrational and rotational quantum numbers than previous water line lists.
Ключевые слова:H$_{2}$$^{16}$O, VoTe, line list, water vapour.
Поступила в редакцию: 11.10.2019 Исправленный вариант: 31.10.2019 Принята в печать: 07.11.2019