RUS  ENG
Full version
JOURNALS // Chelyabinskiy Fiziko-Matematicheskiy Zhurnal // Archive

Chelyab. Fiz.-Mat. Zh., 2018 Volume 3, Issue 2, Pages 212–218 (Mi chfmj100)

Physics

Ceramic materialsbased on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M — Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)

E. A. Bulaeva, Yu. A. Lupitskaya, D. A. Kalganov

Chelyabinsk State University, Chelyabinsk, Russia

Abstract: For barium cerate solid solutions BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$, realised by partial heterovalent substitution of Ce${}^{4+}$ ions by ions of yttrium and rare-earth metals (M — Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$) upon threating in air, the conditions for obtaining are studied. By the method of qualitative X-ray diffraction analysis, it was established that at a final synthesis temperature of 1373 K barium cerate compounds crystallize within the distorted perovskite-type structure. On the basis of X-ray diffraction analysis, parameters characterizing the structure of synthesized perovskite-like phases were determined. The ceramic properties (relative density, porosity, grain size) of the samples sintered at 1773 K were studied.

Keywords: solid solution, barium cerate, heterovalent substitution, X-ray diffraction analysis, perovskite-like phase, ceramics.

UDC: 544.6.018.462.42

Received: 17.02.2018
Revised: 18.03.2018

DOI: 10.24411/2500-0101-2018-13207



© Steklov Math. Inst. of RAS, 2024