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JOURNALS // Chemical Physics and Mesoscopics // Archive

CPM, 2015 Volume 17, Issue 4, Pages 557–564 (Mi chphm235)

Tribochemical properties of the heterogeneous systems containing the surface-modified disperse aluminium

V. V. Taraban, A. G. Syrkov, M. O. Silivanov, E. A. Nazarova

National Mineral Resources University “Mining”, Saint-Petersburg, Russia

Abstract: The priority measurings of friction coefficient (f) and friction force (F$_{\text{òð}}$) are carried out for the heterogeneous systems as oil È-20 with Al-additives modified by triamon (Ò), alkamon and ethylhydridsiloxane according to various programs. It is reduced, with other things being equa, that introducing of triamon underlayers to Al-additives with the external chemisorpted layer of ethylhydridsiloxane lead to the decline of F$_{\text{òð}}$ and f in the system as far as reduction of number of Ò-underlayer from three to one. It is discovered that the use of low-molecular Ò-underlayer in Al-additives is the thin method of regulation of value of summand (from 10.8 to 13.2 Í), answerable in equation for intermolecular forces in the used tribological pair.

Keywords: nanotribology, nonlinear effects, monomolecular layers surfactant, modifying of the aluminum surface, antifrictional effect, intermolecular forces, boundary friction.

UDC: 544.72:538.9



© Steklov Math. Inst. of RAS, 2024