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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2009 Volume 45, Issue 2, Pages 58–67 (Mi fgv1273)

This article is cited in 19 papers

Energetic potential of compositions based on high-enthalpy polynitrogen compounds

D. B. Lempert, G. N. Nechiporenko, S. I. Soglasnova

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia

Abstract: An analysis is performed of the energy properties of solid high-energy systems containing ultrahigh-enthalpy polynitrogen compounds as the only component and in combination with other substances required to produce compositions with necessary operational characteristics. Special attention is given to the restriction of the combustion temperature by introducing substances with a high hydrogen content and a binder into the compositions. Such systems are compared with the best versions of real energetic compositions. As examples, calculations are given for compositions containing both hypothetical compounds (tetraazatetrahedrane N$_4$, octaazacubane N$_8$, trioxyhexazine N$_6$O$_3$, etc.) and real (derivatives of pyrroles, pyrazoles, triazoles, tetrazoles, and other polynitrogen high-enthalpy compounds).

Keywords: specific impulse, combustion temperature, energetic compositions, enthalpy of formation, polynitrogen compounds, oxidizers.

UDC: 662.3.621.453/.457+536.79

Received: 31.03.2008


 English version:
Combustion, Explosion and Shock Waves, 2009, 45:2, 160–168

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