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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2009 Volume 45, Issue 3, Pages 58–65 (Mi fgv1290)

This article is cited in 4 papers

Study of the CL-20 flame structure using probing molecular beam mass spectrometry

A. A. Paletskya, A. G. Tereshchenkoa, E. N. Volkova, O. P. Korobeinichevab, G. V. Sakovichc, V. F. Komarovc, V. A. Shandakovd

a Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
c Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, Biisk, 659322, Russia
d Altai Federal Research-and-Production Center, Biisk, 659322, Russia

Abstract: The CL-20 flame structure at pressures of 0.1 and 0.5 MPa was studied using probing molecular beam mass spectrometry. At a pressure of 0.1 MPa, the gaseous products near the surface of the foamy carbonaceous carcass were found to contain eight species: NO, NO$_2$, CO, CO$_2$, N$_2$, H$_2$O, HCN, and HNCO. At a pressure of 0.5 MPa, NO$_2$ was not found and the concentration profiles of the remaining seven species were measured versus the distance to the carbonaceous carcass. In the CL-20 flame at a pressure of 0.5 MPa, consumption of N$_2$ and CO$_2$ with the formation of NO and HNCO occurred in a zone of width $\approx$0.8 mm from the surface of the carbonaceous carcass. At a pressure of 0.5 MPa, the composition of the gaseous combustion products of CL-20 at a distance of 3–4 mm differed from the composition at thermodynamic equilibrium.

Keywords: flame structure, CL-20, probing molecular beam mass spectrometry.

UDC: 662.612+543.51

Received: 30.05.2008


 English version:
Combustion, Explosion and Shock Waves, 2009, 45:3, 286–292

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