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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2008 Volume 44, Issue 4, Pages 3–12 (Mi fgv1407)

This article is cited in 23 papers

Enhancement of combustion of a hydrogen-air mixture by excitation of O$_2$ molecules to the $a^1\Delta_g$ state state

V. E. Kozlov, A. M. Starik, N. S. Titova

Central Institute of Aviation Motors, State Scientific Center of Russian Federation, 111116, Russia

Abstract: The possibility of increasing the laminar flame velocity in a hydrogen-air mixture by excitation of O$_2$ molecules into the $a^1\Delta_g$ singlet state. The presence of 10% of O$_2$($a^1\Delta_g$) molecules in oxygen is demonstrated to result in noticeable (up to 50%) enhancement of mixture burning. The temperature of combustion products and also the concentrations of H$_2$O, NO, and other constituents increase. The greatest effect of O$_2$($a^1\Delta_g$) molecules is manifested in combustion of lean mixtures; the least pronounced effect is observed in rich mixtures. These effects are caused by intensification of the chain mechanism in the presence of a super-equilibrium amount of excited O$_2$($a^1\Delta_g$) molecules in a hydrogen-air mixture.

Keywords: hydrogen-air mixture, singlet oxygen, laminar flame.

UDC: 62-622:536.46:539.196.5

Received: 01.06.2007
Accepted: 20.12.2007


 English version:
Combustion, Explosion and Shock Waves, 2008, 44:4, 371–379

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