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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2013 Volume 49, Issue 1, Pages 134–137 (Mi fgv16)

This article is cited in 9 papers

Urgent communication

Combustion of furazanotetrazine dioxide

V. P. Sinditskiia, A. V. Burzhavaa, V. Yu. Egorsheva, A. B. Sheremetevb, V. P. Zelenovb

a Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russia
b Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

Abstract: Combustion of furazanotetrazine dioxide (FTDO) was studied in a constant-pressure bomb in the range of pressures 0.1–10 MPa. The thermal decomposition kinetics of FTDO in melt under non-isothermal conditions at temperatures 153–179$^\circ$C was measured. The rate constants of the non-isothermal decomposition are described by an equation with an activation energy of 26.5 kcal/mol. It is concluded from the studies performed that the combustion of FTDO in the entire investigated pressure range obeys the gas-phase model, i.e., the leading combustion reaction is located in the flame.

Keywords: 1,2,5-oxadiazolo[34-e]-1, 2,3,4-tetrazine-4,6-dioxide, furazanotetrazine dioxide (FTDO), combustion rate, combustion mechanism, decomposition kinetics.

UDC: 544.542.2:544.43

Received: 18.07.2012


 English version:
Combustion, Explosion and Shock Waves, 2013, 49:1, 117–120

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