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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2006 Volume 42, Issue 5, Pages 32–45 (Mi fgv1625)

This article is cited in 11 papers

Characteristics of RDX combustion zones at different pressures and initial temperatures

A. A. Zenin, S. V. Finjakov

Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991

Abstract: The RDX burning rates and temperature profiles in the combustion wave are measured with the pressure and initial temperature varied within wide limits. Parameters of combustion waves are found. The gas phase of RDX is demonstrated to have a single-zone structure. Two regimes of RDX combustion are found: a basic regime at $p>$ 0.1 MPa and a special regime at $p\le$ 0.1 MPa. The main characteristics of these regimes are obtained, and the wave regions responsible for the burning rate are determined. Both regimes are characterized by wide reaction zones in the gas phase. The processes of vaporization and decomposition of the condensed phase proceed simultaneously on the burning surface. The fraction of thermal expansion in the reaction layer of this phase is estimated. Laws of RDX gasiffication (pyrolysis) in the combustion wave are found, which turn out to be the same as those for HMX. Distributions of the heat-release rate in the combustion wave (in the reaction layer of the condensed phase and in the gas phase) are obtained. Sensitivity of the burning rate to the initial temperature is measured.

Keywords: burning rate, temperature profiles, heat-release rate, zone parameters, macrokinetics, sensitivity.

UDC: 534.222.2

Received: 11.05.2005
Accepted: 26.04.2006


 English version:
Combustion, Explosion and Shock Waves, 2006, 42:5, 521–533

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