V. K. Smolyakov, V. I. Itin, N. N. Golobokov, N. G. Kasatskii, O. V. Lapshin, Yu. M. Maksimov, O. G. Terekhova, O. A. Shkoda, “Macrokinetics of mechanosynthesis in solid-gas systems. II. Experimental studies. Analysis of results”, Fizika Goreniya i Vzryva, 2005, Volume 41, Issue 5,Pages <nobr>92

This article is cited in 11 papers

Macrokinetics of mechanosynthesis in solid-gas systems. II. Experimental studies. Analysis of results

V. K. Smolyakov^a, V. I. Itin^a, N. N. Golobokov^a, N. G. Kasatskii^a, O. V. Lapshin^b, Yu. M. Maksimov^a, O. G. Terekhova^a, O. A. Shkoda^a

^a Department of Structural Macrokinetics of the Tomsk Scientific Center, Siberian Division, Russian Academy of Sciences, Tomsk, 634021, Russia
^b Institute of Physics of Strength and Materials Science, Siberian Division, Russian Academy of Sciences, Tomsk, 634021, Russia

Abstract: Results from experimental studies of the nonisothermal mechanochemical reaction in the titanium-nitrogen system. Experimental data are compared with simulation results. The effective kinetic parameters of mechanical activation of the reactant and the chemical reaction are determined from analytical relations. It is shown that the developed mathematical model is suitable for the analysis of the macrokinetics of nonisothermal chemical reactions in solid reactant-reactive gas systems.

Keywords: mechanical activation, nonisothermal reaction, titanium nitride, effective kinetic parameters, adequacy of the mathematical model.

UDC: 536.46+541.124

Received: 07.07.2004