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Fizika Goreniya i Vzryva, 2023 Volume 59, Issue 6, Pages 70–81 (Mi fgv2304)

Synthesis and application of hydrophobic silicon dioxide to improve the rheological properties of strovite-based fire-extinguishing agents

Yan Huoa, I. V. Val'tsiferb, A. Sh. Shamsutdinovb, N. B. Kondrashovab, V. V. Zamashchikovc, A. V. P'yankovab

a College of Aerospace and Civil Engineering, Harbin Engineering University, Harbin, China
b Institute of technical Chemistry of Ural branch RAS, Perm, Russia
c Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Abstract: The rheological characteristics of struvite-based fire-extinguishing powder mixtures are comparatively analyzed when using hydrophobic silicon dioxide as a functional filler, obtained during a single-stage synthesis by various methods. Infrared spectroscopy, scanning electron microscopy, low-temperature nitrogen sorption-desorption, and other methods are used to investigate the influence of the synthesis method on the textural and structural properties of hydrophobic functional fillers of fire-extinguishing powder mixtures. It is revealed that the key factor affecting the rheological properties of such mixtures is the uniform distribution of the functional filler over the surface of the particles of a fire extinguishing component (struvite). It is proven that the struvite-based powder composition and the developed functional filler are highly effective for fire extinguishment.

Keywords: fire extinguishing powder mixture, crystalline hydrates, hydrophobic functional filler, performance properties.

UDC: 66.022.34

Received: 09.11.2022
Accepted: 14.12.2022

DOI: 10.15372/FGV2022.9263


 English version:
Combustion, Explosion and Shock Waves, 2023, 59:6, 733–743

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© Steklov Math. Inst. of RAS, 2024