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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 1994 Volume 30, Issue 1, Pages 44–54 (Mi fgv2862)

This article is cited in 8 papers

Velocity of the simplest solid-phase chemical reaction front and internal mechanical stresses

A. G. Knyazeva

Tomsk State University, Department of Physics and Engineering

Abstract: The theory of thermal and mass elasticity is the basis for deriving equations for describing the stationary front of chemical transformations in a deformable medium. Approximate formulas are obtained for the case of a zero-order reaction for calculating the stationary velocity in different particular cases. An increase in the front velocity is shown to be possible, in particular, as a result of direct activation of the chemical reaction at the expense of the work done by the deformation forces. Estimates for the characteristic temperature of the front and combustion are presented. The first value is due to fracture in the front and is defined by the condition of stationary propagation of cracks. In this case, there exist two stationary front velocities. This corresponds to different temperature profiles.

UDC: 536.46+541.124+620.191

Received: 27.05.1993
Accepted: 07.07.1993


 English version:
Combustion, Explosion and Shock Waves, 1994, 30:1, 43–53


© Steklov Math. Inst. of RAS, 2024