N. V. Murav'ev, K. A. Monogarov, V. E. Zarko, P. I. Kalmykov, A. N. Pivkina, “Kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide and binary solution based on it”, Fizika Goreniya i Vzryva, 2019, Volume 55, Issue 5,Pages <nobr>126

This article is cited in 3 papers

Kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide and binary solution based on it

N. V. Murav'ev^a, K. A. Monogarov^a, V. E. Zarko^b, P. I. Kalmykov^c, A. N. Pivkina^a

^a Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia
^b Voevodsky Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Novosibirsk, 630090, Russia
^c Altai Federal Research and Production Center, Biisk, 659322, Russia

Abstract: The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the FTDO/dinitrazapentane (DNP) (75/25%) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. It was found that the thermal decomposition of FTDO and the FTDO/DNP system occurs by a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).

Keywords: FTDO, DNP, differential scanning calorimetry, kinetic parameters, thermal decomposition.

UDC: 547.72:544.4

Received: 14.03.2019
Revised: 17.04.2019
Accepted: 19.04.2019

DOI: 10.15372/FGV20190515