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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2019 Volume 55, Issue 6, Pages 14–18 (Mi fgv627)

This article is cited in 5 papers

Thermochemical and energy characteristics of 1,4-diethylbenzene

D. B. Lempert, I. N. Zyuzin, A. V. Nabatova, A. I. Kazakov, L. S. Yanovskii

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia

Abstract: The standard enthalpy of formation of 1,4-diethynyl)benzene was determined experimentally to be 500.6 $\pm$ 6.7 kJ/mol. Calculations showed that 1,4-di(ethynyl)benzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-di(ethynyl)benzene can be used as the basis to develop an effective dispersant of solid fuel providing an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values that provide the HMX and other azides of N-heterocycles previously proposed for this purpose.

Keywords: 1,4-di(ethynyl)benzene, enthalpy of combustion, enthalpy of formation, solid fuel, ramjet engine, burning temperature.

UDC: 541.11:547.235.5

Received: 11.07.2018
Revised: 05.10.2018
Accepted: 24.10.2018

DOI: 10.15372/FGV20190602


 English version:
Combustion, Explosion and Shock Waves, 2019, 55:6, 644–647

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