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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2019 Volume 55, Issue 6, Pages 50–57 (Mi fgv632)

This article is cited in 1 paper

Direct conversion of chemical energy into electric energy in the combustion of a thin three-layer charge

V. Yu. Barinova, D. Yu. Kovaleva, S. G. Vadchenkoa, O. A. Golosovaa, V. V. Prosyanyukb, I. S. Suvorovb, S. V. Gil'bertb

a Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences Chernogolovka, Chernogolovka, 142432, Russia
b Research Institute of Applied Chemistry, Sergiev Posad, 141313, Russia

Abstract: This paper presents a study of direct conversion of chemical energy into electrical energy during the combustion of a $(80\mathrm{Zr}+20\mathrm{CuO})-(\mathrm{LiF}+\mathrm{CaF}_2+\mathrm{MgF}_2)-(15\mathrm{Zr}+ 85\mathrm{CuO})$ thin three-layer condensed energy system, which is a high-temperature galvanic cell. It is determined that this cell during combustion generates an electric signal with an amplitude of $1.6$ V and a half-width of $15$ s. Its formation mechanism is proposed. A time-resolving X-ray diffraction method is used to identify the phases formed.

Keywords: combustion, EMF of combustion, energy condensing systems, high-temperature galvanic cell.

UDC: 546.543.261

Received: 20.08.2018
Revised: 04.12.2018
Accepted: 26.12.2018

DOI: 10.15372/FGV20190607


 English version:
Combustion, Explosion and Shock Waves, 2019, 55:6, 678–685

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