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JOURNALS // Fizika Goreniya i Vzryva // Archive

Fizika Goreniya i Vzryva, 2019 Volume 55, Issue 6, Pages 58–64 (Mi fgv633)

This article is cited in 11 papers

Effect of coal content and mechanical activation on the combustion of a $\mathrm{Ni}$$\mathrm{Al}$$\mathrm{C}$ system

N. A. Kochetov, A. E. Sytschev

Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, 142432, Russia

Abstract: Effect of carbon content in a $\mathrm{Ni}$$\mathrm{Al}$$\mathrm{C}$ system and preliminary mechanical activation on a burning rate, sample elongation, and yield of the mixture after mechanical activation, as well as on the structural features of combustion products is under study. Combustion in pressed samples from a mechanically preactivated $\mathrm{Ni}+\mathrm{Al}$ mixture at room temperature could not be activated. The introduction of carbon ($2$, $4$, $6\%$ (wt.)) Into the $\mathrm{Ni}+\mathrm{Al}$ reaction mixture allows for combustion in $\mathrm{Ni}$$\mathrm{Al}$$\mathrm{C}$ based pressed samples. Preliminary mechanical activation of the $\mathrm{Ni}+\mathrm{Al}+x\mathrm{C}$ reaction mixture expands a carbon content limit in the mixture at which the combustion of pressed samples is possible. In addition, mechanical activation, as well as an increase in the carbon content in the $\mathrm{Ni}$$\mathrm{Al}$$\mathrm{C}$ system reduces the burning rate. An explanation of the observed relationships is proposed.

Keywords: combustion, mechanical activation, intermetallides, $\mathrm{Ni}+\mathrm{Al}+\mathrm{C}$, nickel aluminide, phase composition of products.

UDC: 536.46

Received: 04.07.2018
Revised: 30.07.2018
Accepted: 12.09.2018

DOI: 10.15372/FGV20190608


 English version:
Combustion, Explosion and Shock Waves, 2019, 55:6, 686–691

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