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Fizika Goreniya i Vzryva, 2025 Volume 61, Issue 2, Pages 68–75 (Mi fgv7202)

Flow instability at charge boundary during nitromethane/polymethyl methacrylate detonation

V. M. Mochalovaa, A. V. Utkina, V. A. Sosikova, S. I. Torunova, D. Yu. Rapotaab, A. V. Savchenkoa, M. Yu. Shakulaac, V. V. Vilkovab, S. A. Koldunova

a Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
b Lomonosov Moscow State University
c Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region

Abstract: Optical methods for recording fast processes are applied to study a flow behind a detonation wave front in a nitromethane/polymethyl methacrylate (NM/PMMA) mixture. It is shown that, an increase in the PMMA concentration leads to an increase in the critical detonation diameter, which, as in pure NM, is determined by the occurrence of reaction failure waves at the charge-shell boundary. A NANOGATE-22/16 high-speed eight-channel sixteen-frame electron-optical camera is used not only to properly study the spatial occurrence and propagation of reaction failure waves, but also to determine their characteristic size. It is shown that unstable flow at the edge of the charge in the NM/PMMA mixture can be stabilized by adding amines or glass microspheres.

Keywords: detonation, critical diameter, detonation instability, nitromethane, PMMA, VISAR, high-speed camera.

UDC: 534.222.2

Received: 05.10.2023
Accepted: 20.12.2023

DOI: 10.15372/FGV2023.9394



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© Steklov Math. Inst. of RAS, 2025