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Fizika Goreniya i Vzryva, 2023 Volume 59, Issue 1, Pages 112–119 (Mi fgv906)

Preparation of nano-RDX-based polymer-bonded explosive and its improved mechanical and detonation properties

G.-Z. Xua, X.-D. Gaob, G.-L. Jinb, D.-Q. Wanga, Z.-M. Zhanga, T.-Y. Tana, Y. Qina, J. Liua, F.-S. Lia

a National Special Super Fine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology
b Gansu Yinguang Chemical Industry Group Co., Ltd., Baiyin 730900, China

Abstract: Industrial micron-size hexahydro-1,3,5-trinitro-1,3,5-triazine (m-RDX) has been widely used in RDX-based polymer-bonded explosives (PBX). However, m-RDX results in poor mechanical properties and adhesive properties of RDX-based PBX m-RDX-PBX). Nano-RDX (n-RDX) has a small particle size and a large specific surface area, which provides a larger contact area with the polymer system. Thus, the porosity and compressive properties of PBX are improved if n-RDX is used in RDX-based PBX (RDX-PBX). In this study, m-RDX and n-RDX are used in RDX-PBX. The microstructure, component content, compressive properties, sensitivity properties, and detonation properties of RDX-PBX are investigated. The results show that n-RDX can make RDX-PBX more compact than m-RDX. The strain of n-RDX-based PBX (n-RDX-PBX) is increased by 39.7% as compared to that of m-RDX-PBX. Meanwhile, the content of each component in n-RDX-PBX is consistent with that of the formula. The sensitivity of n-RDX-PBX is lower as compared to that of m-RDX-PBX, whereas the detonation velocity, detonation pressure, and detonation heat of n-RDX-PBX are equivalent to those of m-RDX-PBX.

Keywords: nano-RDX, RDX-based PBX, compressive property, detonation property, mechanical properties.

UDC: 620.178.7

Received: 11.03.2022
Revised: 18.04.2022
Accepted: 22.06.2022

DOI: 10.15372/FGV20230112


 English version:
Combustion, Explosion and Shock Waves, 2023, 59:1, 103–109

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© Steklov Math. Inst. of RAS, 2024