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JOURNALS // Fizika Tverdogo Tela // Archive

Fizika Tverdogo Tela, 2024 Volume 66, Issue 5, Pages 676–678 (Mi ftt10297)

Semiconductors

High temperature heat capacity of germanate CaEr$_2$Ge$_4$O$_{12}$

L. T. Denisova, D. V. Belokopytova, G. V. Vasil'ev, S. M. Tinkova, V. M. Denisov

Siberian Federal University, Krasnoyarsk

Abstract: According to the standard ceramic technology, CaEr$_2$Ge$_4$O$_{12}$ germanate was obtained from the initial oxides of CaO, Er$_2$O$_3$ and GeO$_2$ by sequential firing in air in the temperature range 1223–1423 K. Its crystal structure was determined using X-ray diffraction (e. g. $P4/nbm$; $a$ = 9.97390(8) $\mathring{\mathrm{A}}$, $b$ = 5.06017(5) $\mathring{\mathrm{A}}$, $V$ = 503.38(1) $\mathring{\mathrm{A}}^3$). The high-temperature heat capacity in the range 320–1050 K was measured by differential scanning calorimetry. Thermodynamic characteristics are calculated using experimental $C_p(T)$ data.

Keywords: calcium-erbium germanate, solid-phase synthesis, heat capacity, thermodynamic properties.

Received: 06.02.2024
Revised: 10.04.2024
Accepted: 13.04.2024

DOI: 10.61011/FTT.2024.05.58070.20



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© Steklov Math. Inst. of RAS, 2025