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Fizika Tverdogo Tela, 2024 Volume 66, Issue 6, Pages 1000–1004 (Mi ftt10346)

Low dimensional systems

Raman scattering behavior of hybrid polymeric complexes of polyvinyl alcohol with CuCl$_2$ and Cu(OH)$_2$/CuO

I. Yu. Prosanova, V. A. Volodinbc

a Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
b Rzhanov Institute of Semiconductor Physics, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia
c Novosibirsk State University, Novosibirsk, Russia

Abstract: It is shown that Raman spectra of PVA-CuCl$_2$ and PVA-Cu(OH)$_2$/CuO complexes recorded at 514.5 nm excitation have similar shape with prominent background and broad band at 1590 cm$^{-1}$. They are identical to spectra of PVA complexes' with other inorganic compounds, spectra of different carbonaceous materials – polyacetilene, graphite and nanotubes and PVA's SERS spectrum. This result is regarded as a consequence of one-dimensionality of investigated materials. Raman bands of PVA, Cu(OH)$_2$/CuO, and CuO are present in PVA-Cu(OH)$_2$ complexes' spectra at 1064 nm excitation.

Keywords: low-dimensional systems, SERS.

Received: 04.05.2024
Revised: 04.05.2024
Accepted: 07.05.2024

DOI: 10.61011/FTT.2024.06.58257.116



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© Steklov Math. Inst. of RAS, 2025