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Fizika Tverdogo Tela, 2015 Volume 57, Issue 1, Pages 124–128 (Mi ftt11268)

This article is cited in 10 papers

Phase transitions

Polymorphism of Ga–In alloys in nanoconfinement conditions

E. N. Latyshevaa, A. L. Pirozerskiia, E. V. Charnayaa, Yu. A. Kumzerovb, A. V. Fokinb, A. I. Nedbaia, A. S. Bugaevc

a Institute of Physics, Saint-Petersburg State University
b Ioffe Institute, St. Petersburg
c Moscow Institute of Physics and Technology, State University, Institutskii per. 9, Dolgoprudnyi, Moscow oblast, 141700, Russia

Abstract: The results of acoustic investigations of the melting and crystallization of indium-gallium alloys of different compositions embedded in porous glass matrices with a pore size of 18 nm are presented. It was shown that the formation of the $\alpha$ and $\beta$ crystalline modifications of gallium is possible depending on the alloy composition in nanopores. The fraction of $\beta$-Ga increased as the indium concentration in the alloy increased. Stabilization of $\beta$-Ga in conditions of confined geometry was revealed. Broadening of the melting region of the $\alpha$ phase of gallium and narrowing of the melting region of $\beta$-Ga, as compared with the corresponding bulk alloys, were observed.

Received: 03.07.2014


 English version:
Physics of the Solid State, 2015, 57:1, 131–135

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