Yu. V. Gerasimova, A. S. Oreshonkov, A. A. Ivanenko, M. S. Molokeev, L. I. Isaenko, I. N. Flerov, E. V. Bogdanov, M. V. Gorev, A. V. Kartashev, A. S. Krylov, “Structural, spectroscopic, and thermophysical investigations of the oxyfluorides CsZnMoO$_3$F$_3$ and CsMnMoO$_3$F$_3$ with the pyrochlore structure”, Fizika Tverdogo Tela, 2014, Volume 56, Issue 3,Pages 577

Lattice dynamics

Structural, spectroscopic, and thermophysical investigations of the oxyfluorides CsZnMoO$_3$F$_3$ and CsMnMoO$_3$F$_3$ with the pyrochlore structure

Yu. V. Gerasimova^a, A. S. Oreshonkov^a, A. A. Ivanenko^a, M. S. Molokeev^a, L. I. Isaenko^b, I. N. Flerov^ac, E. V. Bogdanov^a, M. V. Gorev^ac, A. V. Kartashev^a, A. S. Krylov^a

^a L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk
^b Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
^c Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk

Abstract: The structure, infrared and Raman spectra, heat capacity, and thermal expansion have been investigated. It has been shown that, down to liquid-helium temperatures, the cubic pyrochlore structure of the CsZnMoO$_3$F$_3$ and CsMnMoO$_3$F$_3$ oxyfluorides remains stable. The influence of cation substitution on individual features of the properties of the oxyfluorides has been analyzed.

Received: 02.08.2013