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Fizika Tverdogo Tela, 2013 Volume 55, Issue 8, Pages 1626–1632 (Mi ftt12526)

Polymers

On the mechanisms of photogeneration of charge carriers in PEPC–C$_{60}$ composites

M. A. Zabolotnyi, Yu. M. Barabash, O. P. Dmitrenko, N. P. Kulish, N. A. Davidenko, S. L. Studzinsky, A. P. Olasyuk, A. V. Demchenko

National Taras Shevchenko University of Kyiv

Abstract: Photogeneration of electric charge carriers at high strengths of the external electric field and the temperature of transition to the viscous-flow state $(T_{\mathrm{visc}})$ of thin PEPC–C$_{60}$ composite films obtained by casting from a toluene solution have been studied. The rheology of the composite films has been investigated by the nondestructive optical method. The consistent correlated change in the values of $T_{\mathrm{visc}}$ and the effective temperature in the expression for the photogeneration quantum yield $(T_0)$ in the Meltz representation with variations in the C$_{60}$ concentration has been established. The difference between $T_{\mathrm{visc}}$ and $T_0$ in thin composite films does not exceed 2–3% of $T_{\mathrm{visc}}(T_0)$.

Received: 26.12.2012


 English version:
Physics of the Solid State, 2013, 55:8, 1739–1746

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