XX Anniversary Meeting on the Use of Neutron Scattering in Condensed Matter Research (RNICS-2008), Gatchina (October 13-18, 2008) Functional and nanostructured materials
Temperature dependences of the order parameter for sodium nitrite embedded into porous glasses and opals
Abstract:
The temperature dependences of the order parameter $\eta(T)$ for sodium nitrite NaNO$_2$ embedded in porous glasses with average pore diameters of 320 and 20 nm, as well as in artificial opals, have been investigated. It has been demonstrated that the dependence $\eta(T)$ for sodium nitrite in the porous glass almost coincides with that for the bulk material, whereas this dependence for NaNO$_2$ in opals differs substantially from that observed in the bulk material and from those previously determined for sodium nitrite in porous glasses with average pore diameters of 3 and 7 nm. It has been revealed that the dependence of the order parameter for sodium nitrite in opals exhibits a temperature hysteresis (approximately equal to 8 K). The temperature dependence $\eta(T)$ has been described using a simple model, which takes into account the nanopore diameter distribution existing in artificial opals.