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Fizika Tverdogo Tela, 2021 Volume 63, Issue 11, Pages 1795–1800 (Mi ftt7949)

XXI All-Russian School-Seminar on Condensed Matter Physics (SPFKS-21), Yekaterinburg, March 18-25, 2021
Magnetism

Magnetic and magnetocaloric properties of Ho$_{1-x}$Y$_{x}$(Co$_{0.84}$Fe$_{0.16}$)$_{2}$ compounds

M. S. Anikina, E. N. Tarasova, D. S. Neznakhina, M. A. Semkinab, N. V. Seleznevaa, S. V. Andreeva, M. V. Ragozinaab, A. V. Zinina

a Institute of Natural Sciences, Ural Federal University named after the first President of Russia Boris Yeltsin, Ekaterinburg
b M.N. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

Abstract: Ñrystal structure, temperature and field dependences of magnetization, high-field susceptibility, and magnetocaloric effect (MCE) of Ho$_{1-x}$Y$_{x}$(Co$_{0.84}$Fe$_{0.16}$)$_{2}$ polycrystalline compounds ($x$ = 0 – 1) in magnetic fields up to 90 kOe in a temperature range of 5 – 400 K are investigated. An analysis of temperature dependences of magnetization $(\sigma)$ showed that, depending on the yttrium content $(x)$, up to three magnetic phase transitions can be simultaneously present in the studied samples: spin-reorientation $(T_\mathrm{sr})$, magnetic compensation point $(T_\mathrm{comp})$, and Curie temperature $(T_C)$. The temperature dependence of the high-field susceptibility $(\chi_{hf})$ of all samples with $x<1$ has an extremum in the vicinity of 100 K, where a significant MCE is observed, associated with a sharp change in the magnetization of the rare-earth sublattice. The temperature dependences of the magnetic entropy change $(\Delta S_m)$ and the adiabatic temperature change $(\Delta T_{ad})$ have a complex shape and reflect all the above-mentioned magnetic phase transitions and four types of magnetic structures observed at different $x$.

Keywords: magnetic properties, direct and inverse magnetocaloric effect, adiabatic temperature change, magnetic moment, Laves phases, Curie temperature, compensation point, spin-reorientation transition.

Received: 08.07.2021
Revised: 13.07.2021
Accepted: 16.07.2021

DOI: 10.21883/FTT.2021.11.51578.05s



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