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Fizika Tverdogo Tela, 2021 Volume 63, Issue 10, Pages 1447–1450 (Mi ftt7975)

Metals

Electron density fluctuations and phase transition in $\alpha$-titanium

A. A. Povzner, A. G. Volkov

Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russia

Abstract: It is shown that the topological features of the electronic structure of $\alpha$-titanium lead to the appearance of temperature-induced fluctuations of the electron density, which disappear near the temperature of the phase transition from the HCP ($\alpha$-phase) to the BCC ($\beta$-phase). The experimen-tally observed linear temperature increase in the magnetic susceptibility in the beta-phase and its jump during the transition to the $\beta$-phase are described. The considered fluctuation pattern de-scribes a sharp decrease in the electron entropy and softening of the longitudinal phonon modes associated with the electron-ion interaction. It is shown that the temperature of the phase transition in $\alpha$-titanium depends on the position of the Fermi level, which can be changed by introducing impurities.

Keywords: titanium, fluctuations, topology, phase transition.

Received: 22.03.2021
Revised: 11.05.2021
Accepted: 24.05.2021

DOI: 10.21883/FTT.2021.10.51389.058


 English version:
Physics of the Solid State, 2021, 63:12, 1765–1768

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© Steklov Math. Inst. of RAS, 2024