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Fizika Tverdogo Tela, 2021 Volume 63, Issue 10, Pages 1505–1513 (Mi ftt7984)

This article is cited in 1 paper

Magnetism

Phenomenon of low-dimensional magnetism in C$K\alpha$, N$K\alpha$, and O$K\alpha$ spectra of carbonates and nitrates obtained by the electron probe microanalysis (EPMA)

I. M. Kulikova, O. A. Nabelkin, V. A. Ivanov, I. A. Filenko

Institute of Mineralogy, Geochemistry and Crystal Chemistry of Rare Elements, Moscow, Russia

Abstract: Primary C$K\alpha$, N$K\alpha$, and O$K\alpha$ spectra are recorded in single crystals of carbonates, nitrites, and nitrates by the electron probe microanalysis (EPMA). The shift and width of the $K\alpha$ lines are used for determining the patterns of variations in charge and spin densities around the emitting atom in the low-dimensional magnetics. The method has made it possible to obtain experimental knowledge about the indirect exchange interaction in the study samples of single crystals, including micron-sized ones at room temperature. The structure of resonance levels (plasmons) is identified in the nitrogen spectra in nitrates and nitrites in the conduction bands.

Keywords: $K\alpha$-spectra of carbon, nitrogen, oxygen, carbonates, nitrates, nitrites, spin density, charge density, superexchange, electron probe microanalysis.

Received: 25.12.2020
Revised: 17.05.2021
Accepted: 18.05.2021

DOI: 10.21883/FTT.2021.10.51397.274


 English version:
Physics of the Solid State, 2021, 63:11, 1695–1703

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© Steklov Math. Inst. of RAS, 2024