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Fizika Tverdogo Tela, 2021 Volume 63, Issue 4, Pages 465–470 (Mi ftt8145)

This article is cited in 4 papers

Semiconductors

Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)

L. B. Vedmid'ab, O. M. Fedorovaa, V. B. Balakirevac, V. A. Vorotnikovbc, V. F. Balakireva

a Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Ekaterinburg, Russia
b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg, Russia
c Institute of High-Temperature Electrochemistry, RAS, Ekaterinburg, Russia

Abstract: Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ manganites ($x$ = 0; 0.15; 0.25) were synthesized by the solid-phase method at a temperature of 1250$^{\circ}$C and have an orthorhombic perovskite-like structure (space group $Pbnm$). A comprehensive study of the effect of praseodymium substitution with strontium on the temperature features of the transformation of the crystal structure of the studied perovskites was performed using high-temperature radiography and differential thermal analysis. It was determined that the temperature of the Jahn-̉eller effect significantly decreases with the introduction of strontium. It is established that all samples have a semiconductor character of conductivity. Strontium doping significantly increases the electrical conductivity of praseodymium manganites, especially at temperatures below 450$^{\circ}$C.

Keywords: strontium, rare earth element manganites, perovskites, Jahn–̉eller effect, electrical conductivity.

Received: 10.12.2020
Revised: 17.12.2020
Accepted: 17.12.2020

DOI: 10.21883/FTT.2021.04.50710.258


 English version:
Physics of the Solid State, 2021, 63:4, 660–665

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© Steklov Math. Inst. of RAS, 2024