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Fizika Tverdogo Tela, 2021 Volume 63, Issue 4, Pages 471–474 (Mi ftt8146)

This article is cited in 2 papers

Semiconductors

Heat capacity and thermodynamic functions of GdGaTi$_{2}$O$_{7}$ in the temperature range of 320–1000 K

L. T. Denisovaa, M. S. Molokeevab, L. G. Chumilinaa, V. V. Ryabovc, V. M. Denisova

a Siberian Federal University, Krasnoyarsk, Russia
b L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia
c Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Ekaterinburg, Russia

Abstract: Titanate GdGaTi$_{2}$O$_{7}$ has been obtained from the initial oxides Gd$_{2}$O$_{3}$, Ga$_{2}$O$_{3}$, and TiO$_{2}$ by the solid-state synthesis via annealing in air at temperatures of 1273 and 1573 K. The crystal structure of the titanate has been refined by X-ray diffraction. The high-temperature (320–1000 K) heat capacity of the compound has been measured by differential scanning calorimetry. Based on the experimental dependence $C_p = f(T)$, the main thermodynamic functions of the titanate have been calculated.

Keywords: rare-earth titanates, solid-state synthesis, high-temperature heat capacity, thermodynamic functions.

Received: 16.12.2020
Revised: 16.12.2020
Accepted: 18.12.2020

DOI: 10.21883/FTT.2021.04.50711.261


 English version:
Physics of the Solid State, 2021, 63:4, 534–537

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© Steklov Math. Inst. of RAS, 2024