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Fizika Tverdogo Tela, 2019 Volume 61, Issue 12, Pages 2364–2368 (Mi ftt8569)

This article is cited in 5 papers

International Conference ''Mechanisms and Nonlinear Problems of Nucleation, Growth of Crystals and Thin Films'' dedicated to the memory of the outstanding theoretical physicist Professor V.V. Slezov (Proceedings) St. Petersburg, July 1-5, 2019
Magnetism

Glycine–nitrate synthesis of solid solutions of barium–strontium metatitanate

D. N. Belyshevaa, O. Yu. Sinel'shchikovaa, N. G. Tyurninaa, Z. G. Tyurninaa, S. I. Sviridova, A. V. Tumarkinb, M. V. Zlygostovb, V. L. Ugolkova

a I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences, St. Petersburg
b Saint Petersburg Electrotechnical University "LETI"

Abstract: The effect of the compound of glycine-nitrate compositions on the completeness of the formation of solid solutions of barium-strontium metatitanate was studied. It was shown that the decomposition of all examined glycine-nitrate compositions begins at a temperature of 180$^{\circ}$C, but depending on the glycine content and the pH, it has a different character. The optimal condition for the formation of single-phase products is the volumetric combustion mode, achieved when the content of the reducing agent is higher than the oxidizing agent in the composition. Such compositions make it possible to obtain nanosized powders of Ba$_{1-x}$Sr$_{x}$TiO$_{3}$ solid solutions (0 $\le x\le$ 0.4) by calcination at a temperature of 550$^{\circ}$C, as well as to introduce them into composites based on porous magnetic glass, avoiding the interaction between the formed ferroelectric phase and the glass matrix.

Keywords: glycine-nitrate synthesis, barium-strontium metatitanate, ferromagnetic porous glasses, multiferroics.

Received: 16.07.2019
Revised: 16.07.2019
Accepted: 25.07.2019

DOI: 10.21883/FTT.2019.12.48555.11ks


 English version:
Physics of the Solid State, 2019, 61:12, 2371–2375

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