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JOURNALS // Fizika Tverdogo Tela // Archive

Fizika Tverdogo Tela, 2019 Volume 61, Issue 7, Pages 1346–1351 (Mi ftt8765)

This article is cited in 16 papers

Phase transitions

The high-temperature polymorphism of ZrO$_{2}$

V. P. Gorelov

Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia

Abstract: An analysis of primary literature sources shows that there is only one reliable report on the observation of the cubic ZrO$_{2}$ phase by the X-ray method under oxidizing conditions. This phase is observed at temperatures not lower than 2500$^\circ$C. All other reports on the observation of a phase transition around 2300$^\circ$C are reliable only in relation to the existence of a transition at this temperature, but this transition is to the $t$' tetragonal phase rather than to the cubic one. The conclusion is that the following four polymorphic modifications are present in ZrO$_{2}$ under the standard pressure: monoclinic $(m)$, two tetragonal ($t$ and $t$'), and cubic $(c)$ phases that are converted into each other with an increase in the temperature.

Received: 21.02.2019
Revised: 12.03.2019
Accepted: 12.03.2019

DOI: 10.21883/FTT.2019.07.47849.383


 English version:
Physics of the Solid State, 2019, 61:7, 1288–1293

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© Steklov Math. Inst. of RAS, 2024