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Fizika Tverdogo Tela, 2018 Volume 60, Issue 9, Page 1793 (Mi ftt9085)

Impurity centers

Electron paramagnetic resonance of Cr$^{3+}$ ions in single crystals of yttrium aluminum borate YAl$_{3}$(BO$_{3}$)$_{4}$

A. Vorotynova, Ya. Shiyana, I. Gudima, L. Bezmaternykha, O. Vorotynovab

a Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
b Siberian Federal University, Krasnoyarsk, Russia

Abstract: Single crystal of yttrium aluminum borate YAl$_{3}$(BO$_{3}$)$_{4}$ doped with chromium ions (1 at.%) was studied using electron paramagnetic resonance spectroscopy. It is shown that chromium ions introduced into the sample occupy yttrium ion sites in the crystal structure. The parameters of the spin Hamiltonian of Cr$^{3+}$ ions in the YAl$_{3}$(BO$_{3}$)$_{4}$ matrix are determined at different temperatures. The sign of the fine structure parameter $D$ allows the conclusion that the chromium ions in YAl$_{3}$(BO$_{3}$)$_{4}$ single crystals have an easy-plane anisotropy.

Received: 21.03.2018

Language: English

DOI: 10.21883/FTT.2018.09.46399.075


 English version:
Physics of the Solid State, 2018, 60:9, 1839–1843

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© Steklov Math. Inst. of RAS, 2024