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JOURNALS // Fizika Tverdogo Tela // Archive

Fizika Tverdogo Tela, 2018 Volume 60, Issue 3, Pages 618–622 (Mi ftt9288)

This article is cited in 9 papers

Thermal properties

High-temperature heat capacity of germanates Pr$_{2}$Ge$_{2}$O$_{7}$ and Nd$_{2}$Ge$_{2}$O$_{7}$ within 350–1000 K

L. T. Denisova, L. A. Irtyugo, V. V. Beletskii, N. V. Belousova, V. M. Denisov

Institute of Non-Ferrous Metals and Materials Science, Siberian Federal University

Abstract: Pr$_{2}$Ge$_{2}$O$_{7}$ and Nd$_{2}$Ge$_{2}$O$_{7}$ were obtained via solid-phase synthesis from Pr$_{2}$Ge$_{2}$O$_{7}$ and Nd$_{2}$Ge$_{2}$O$_{7}$ with multistage firing in air within 1273–1473 K. A temperature effect on molar heat capacity of the oxide compounds was measured with a differential scanning calorimetry. Their thermodynamic properties were calculated from the $C_P = f (T)$ dependences.

Received: 27.09.2017

DOI: 10.21883/FTT.2018.03.45571.285


 English version:
Physics of the Solid State, 2018, 60:3, 626–630

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