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Fizika Tverdogo Tela, 2017 Volume 59, Issue 8, Pages 1594–1597 (Mi ftt9498)

Phase transitions

Kinetics of the growth of filamentary KH$_{2}$PO$_{4}$ crystals on a seed crystal

E. K. Titaevaa, M. S. Kuritsynb, A. N. Noskovaa, V. N. Portnova

a National Research Lobachevsky State University of Nizhny Novgorod
b Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod

Abstract: At oversaturations exceeding the inert range end for face $\{101\}$ due to the presence of admixture Al(NO$_{3}$)$_{3}$ $\cdot$ 9H$_{2}$O, a new phase is observed during the growth of this face in the form of filamentary crystals. Some experimental dependences of the growth rate of filamentary potassium dihydrophosphate (KH$_{2}$PO$_{4}$ ) crystals on the oversaturation have been obtained at different admixture concentrations. The growth of filamentary crystals occurs by the mechanism of two-dimensional nucleation. Their formation is governed by the effect of [AlHPO$_{4}$]$^{+}$ complexes in the form of Cabrera and Vermilyea stoppers.

Received: 16.08.2016
Revised: 20.12.2016

DOI: 10.21883/FTT.2017.08.44763.332


 English version:
Physics of the Solid State, 2017, 59:8, 1619–1622

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© Steklov Math. Inst. of RAS, 2024