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JOURNALS // Fizika Tverdogo Tela // Archive

Fizika Tverdogo Tela, 2017 Volume 59, Issue 6, Pages 1243–1246 (Mi ftt9567)

This article is cited in 8 papers

Thermal properties

High-temperature heat capacity of oxides of the CuO–V$_{2}$O$_{5}$ system

L. T. Denisova, N. V. Belousova, V. M. Denisov, N. A. Galiakhmetova

Institute of Non-Ferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russia

Abstract: CuV$_{2}$O$_{6}$ and Cu$_{2}$V$_{2}$O$_{7}$ compounds have been produced from initial components CuO and V$_{2}$O$_{5}$ by solid-phase synthesis. The high-temperature heat capacity of the oxide compounds has been measured using differential scanning calorimetry. The thermodynamic properties (the enthalpy change, the entropy change, and the reduced Gibbs energy) have been calculated using experimental dependences $C_P = f(T)$. It is found that there is a correlation between the specific heat capacity and the composition of oxides of the CuO–V$_{2}$O$_{5}$ system.

Received: 07.11.2016

DOI: 10.21883/FTT.2017.06.44500.407


 English version:
Physics of the Solid State, 2017, 59:6, 1270–1274

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