V. V. Mesilov, M. S. Udintseva, S. N. Shamin, S. V. Naumov, S. V. Telegin, B. A. Gizhevskii, V. R. Galakhov, “Determination of charge states of cobalt ions in nanostructured GdBaCo$_{2}$O$_{5.5}$ cobaltites by means of X-ray absorption spectroscopy”, Fizika Tverdogo Tela, 2017, Volume 59, Issue 4,Pages 810

This article is cited in 5 papers

Atomic clusters

Determination of charge states of cobalt ions in nanostructured GdBaCo$_{2}$O$_{5.5}$ cobaltites by means of X-ray absorption spectroscopy

V. V. Mesilov^a, M. S. Udintseva^b, S. N. Shamin^a, S. V. Naumov^a, S. V. Telegin^a, B. A. Gizhevskii^a, V. R. Galakhov^a

^a Institute of Metal Physics, Ural Division of the Russian Academy of Sciences, Ekaterinburg
^b Urals State University of Railway Transport, Ekaterinburg

Abstract: X-ray absorption spectroscopy has been applied for a characterization of charge states of cobalt ions of nanostructured GdBaCo$_{2}$O$_{5.5}$ complex oxides. The analysis of experimental and theoretical data has allowed establishing a reduction in the oxidation degree from Co$^{3+}$ to Co$^{2+}$ for a part of cobalt ions in GdBaCo$_{2}$O$_{5.5}$ nanoceramics obtained by torsion under pressure.

Received: 19.09.2016

DOI: 10.21883/FTT.2017.04.44287.353