A. A. Titov, A. N. Titov, S. G. Titova, S. V. Pryanichnikov, D. S. Chezganov, “Cointercalation of titanium dichalcogenides with transition metals and copper”, Fizika Tverdogo Tela, 2017, Volume 59, Issue 1,Pages <nobr>138

This article is cited in 3 papers

Phase transitions

Cointercalation of titanium dichalcogenides with transition metals and copper

A. A. Titov^a, A. N. Titov^ab, S. G. Titova^c, S. V. Pryanichnikov^c, D. S. Chezganov^b

^a Institute of Metal Physics, Ural Division of the Russian Academy of Sciences, Ekaterinburg
^b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
^c Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Yekaterinburg

Abstract: Сointerсalated materials are studied, obtained by introducing copper into a TiSe$_2$ lattice preintercalated with transition metals $M$ = Mn, Fe, Co, or Ni. The analysis of the state of cointercalated systems at 950$^\circ$C shows that copper reduces manganese and iron, but it is incapable of reducing cobalt or nickel. To explain the results, the values of the binding energy of hybrid states $M$3$d$/Ti3$d$ are compared.

Received: 02.02.2016
Revised: 10.03.2016

DOI: 10.21883/FTT.2017.01.43964.35